(Proposal ID) S17A-131 (PI) de Mooij, Ernst (Proposal Title) Comparative Exoplanetology: Probing the Atmospheres of Hot Saturns (Abstract) Characterizing exoplanet atmospheres presents a formidable challenge, primarily due to the extreme brightness contrast between the planet and the host star. However, transmission spectroscopy during transits, when stellar light passes through a planet's atmosphere, offers a rare opportunity to identify the presence of atomic and molecular species and other atmospheric features. Here we propose to extend the technique to characterize atmospheres of two Saturn-mass planets using HDS, specifically targeting the Sodium and Potassium lines at optical wavelengths. Both planets have a very low surface gravity, resulting in very extended atmospheres. Low-resolution space-based observations hint at the presence of alkali metals. These high-resolution observations will allow us to not only detect the species, but also to use the line-broadening and positions to determine the temperature-pressure profile as well as the wind speeds in their upper atmospheres. In addition, we will investigate the alignment between the planet's orbit and stellar rotation using the Rossiter- McLaughlin effect. Both planets have relatively large orbital separations and small mass ratios, resulting in long timescales for the alignment of the convective stellar envelope, which has been invoked to explain high obliquities.